Tag: synthetic lubricants

How to Select the Right Grease

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Selecting a grease or lubricant is one of the most crucial decisions you make in regards to any machine. Your selection might make the difference between cost savings, reduced downtime, or significant unexpected costs and failures. For oil lubricants, many OEMs specify what product or what type of product is recommended for each component of their equipment. This simplifies the selection process. However, OEM grease specifications are much broader. Most of the time OEMs simply recommend the National Lubrication Grease Institute (NLGI) specification.

This presents both flexibility and options, but also introduces more room erroneous decision-making and poor lubrication. Simply using the NLGI grade is not enough. You have to look at other factors to ensure you grease and machine work properly and does not fail. We will look at some key factors that every operator needs to consider.

Base Oil Viscosity

A grease is composed of 3 ingredients: thickener, oil, and additives. The NLGI number indicates the thickness of the thickener, but does not specify the viscosity of the thickened base oil. The underlying base oil has its own viscosity just like any lubrication oil. If a piece of a equipment calls for a certain lubricating oil with a specific viscosity, it is easy to find a grease that has the same base oil viscosity and similar additive package.

If viscosity requirements are not specified, you can use the chart below (courtesy of ExxonMobil and Noria).

The two factors required are operating temperature and DN or NDm, which are the bearing speed factors. To calculate those speed factors, simply use the following formula:

  • DN = (rpm)*(bearing bore) and
  • NDm = (rpm)*((bearing bore + outside diameter) / 2)

The intersection of DN and Temperature will point you towards the required ISO viscosity. This chart assumes viscosity index.

Base Oil Type and Additives

Once a viscosity is identified, you need to figure out what additives and base oil you need. Similar to oil lubricants you must assess your operations and figure what additives are necessary or unnecessary. For example, light loads and high-speed applications do not require a grease with extreme pressure (EP) additives, but a heavily loaded application will need those EP additives. The chart below breaks down the needed additives for various bearings.

Courtesy of Noria

Most greases use mineral oil and only require mineral oil. However, synthetic base oils are recommended for certain extreme temperature applications. Applications with low or high operating temperatures or a wide range of temperatures, a synthetic base oil is recommended. Synthetic base oil greases are also recommended for users who want to longer regreasing intervals.

Grease Thickener

Unlike lubricating oils, greases include thickeners. The two factors that distinguish grease are type and consistency. As mentioned earlier, consistency is based on the NLGI scale. The scale ranges from 000 (most fluid) to 6 (least fluid). The most common and most recommended NLGI grade is #2. Most OEMs specify the NLGI grade and matching that number is a simple process (especially if you require a NLGI 2 grease).

The other factor for thickeners is the type of thickener. The differences between each type of thickener are present pros and cons for each application. The most common types are lithium soap, lithium complex, and polyurea. Lithium soap greases are low-cost general-purpose grease and perform well in general applications. Lithium complex is similar to lithium soap, but is preferred for applications with higher operating temperatures. Polyurea greases have good high-temperature properties and have high oxidation stability and bleed resistance. When switching greases, it is important to understand thickener compatibility to make sure the new grease does not fail.

Cost and Other Considerations

When purchasing a grease, a basic lithium grease will be cheaper than a sophisticated polyurea grease. It is up to you to determine the tradeoffs between grease costs and performance gains/losses. Purchasing a higher quality grease may lead to longer regreasing intervals and less machine failure.

To save costs, consolidating greases may be wise, but be wary of over-consolidation. This may result in some machines not using an appropriate grease.

Other attributes should be considered depending on the application. Some grease exclusive attributes include:

  • Drop Point
  • Mechanical Stability
  • Water Washout
  • Bleed Characteristics
  • Pumpability

Certain attributes are focused specifically on heavy loads and should be considered for heavy load-low speed applications. These include:

  • Four-Ball Tests
  • Timken OK Load

Additionally, industry specific requirements will also dictate grease selection. These industries have strict requirements and require greases to be certified by certain 3rd-party regulators:

Conclusion

Unlike oils, greases have many more factors for product selection. These factors should be considered for each application as each grease is designed and manufacturer specifically for each application and have a delicate balance of thickener, oil, and additives.

Twin Specialties carries a wide variety of greases to meet you application needs. We work directly with you to make sure we provide the right product that delivers performance while being mindful of the total cost of grease and maintenance. Contact Twin Specialties to learn more about our grease product lines.

Lubricants for Cold Weather

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During the winter months and in cold weather regions, operators will face cold starts regularly and must select lubricants that ensure proper performance and protect your machine or engine. We will focus on key features that will differentiate lubricants that excel in cold weather and lubricants that will lead to machine or engine failure.

Viscosity

Not all cold starts are equal. There are varying temperatures and the lubricant you need will depend on the ambient temperature. If temperatures are below -20 C/- 4 F, it is recommended to use base oils that can flow in low temperatures. For engine oils, using an SAE 0W or SAW 5W grade lubricant is recommended. When the temperature drops below -30 C/- 22 F, operators should use a SAE 0W or SAE 5W lubricant, but whose base oil is a synthetic base stock and/or a base oil that is considered “multi-grade” or “multi-viscosity.”

Many of these multi-viscosity and multi-grade lubricants are designed for extreme weather conditions including cold start conditions. These lubricants maintain their viscosity better than conventional lubricants. Generally, multi-viscosity lubricants exhibit viscosity characteristics found in 2 different ISO viscosity grades (i.e. ISO 32-46) and multi-grade lubricants exhibit viscosity characteristics found in 3 different ISO viscosity grades (i.e. ISO 32-46-68).

Viscosity Index

When the temperature drops, the lubricant becomes more viscous, thus making it more difficult to circulate and flow through the engine or machine. Having a lubricant with a high viscosity index, defined as a viscosity index greater than 130, ensures that your lubricant better maintains its viscosity in extreme temperatures. Lubricants with high viscosity indices have either a highly refined or synthetic base stock or include viscosity index improver additives.

Monograde lubricants will have viscosity indices in the 95-105 range and will not perform as well as in cold start conditions. Many operators will use different monograde lubricants depending on the ambient temperature. This may cause issues with change outs and cold temperature properties.

Pour Point

As mentioned earlier, not all cold starts are created equal. In colder temperatures, a lubricant’s pour point could be the difference between success and failure. Pour point is defined as when a lubricant no longer flows and congeals. When operating in temperatures below -30 C/-22 F, it is imperative to use a lubricant with a pour point lower than -50 C/-58 F. Similar to viscosity index, lubricants with highly refined or synthetic base stocks have lower pour points. Some lubricants are manufactured with pour point depressants that prevent wax formation and the congealing of the lubricant.

Oil Integrity and Storage

While you can meticulously select the perfect lubricant based on your OEM requirements, ambient climate, and budget, it could be costly if you do not maintain it properly. Just like any oil, it is important to regularly check the oil for cleanliness and contamination. Taking regular samples is key to ensure your lubricant and machine is in good health. When storing lubricants. It is helpful to store the lubricant indoors or in a warmer environment so that it flows easily during start-up. Proper storage will also protect against contamination. If contaminated, the additives such as VI improvers or pour point depressants may not be as effective and could hurt lubricant performance.

A Guide to Base Oil Groups

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In any oil-based lubricant the base oil will compose 80-99% of the product you use. What are differences in the main ingredient of your lubricant? The American Petroleum Institute classifies base oils into 5 groups. These classifications are based on the chemical composition of the base oil and the treatment of the base oil.

If a base oil is classified as Group I-III, that base oil will be composed of crude oil that has been treated. The differences depend on the treatment processes applied to the oil.

Petroleum Base Oils

Group I

Group I base oils are the least refined base oil. Two main characteristics of Group I base oils are that they are composed of less than 90% saturates and/or greater than 0.03% sulfur. If either of these conditions are satisfied, then the base oil will be classified as Group I. The only process that is used is solvent refining, which allows Group I base oil products to be cheaper than their more refined equivalents. These are generally used for less-demanding applications and could be ideal for applications where lubricant consumption is high.

Group II

Group II base oils are more refined than Group I. In addition to solvent refining, these oils are also hydrocracked purify the oil. Unlike Group I base oils, these base oils must contain over 90% saturates and less than 0.03%. The greater percentage of saturates gives these lubricants better antioxidation properties than Group I base oils.

Failure to meet either of these requirements will result in a Group I classification. These products also have a viscosity index of 80-120. These oils have good performance in volatility, oxidation stability, wear prevention, and flash point. They only have fair performance in cold temperature environments. Given costs of treatment today, Group II lubricants are most commonly used today and many users have switched from Group I oils to Group II oils.

Unofficially, there is a Group II+ that are composed of high-end Group II base oils. These base oils must have a viscosity index of 110-120 to be considered Group II+.

Group III

Group II base oils must meet the same conditions (saturates and sulfur) as Group II, but also must have a viscosity index greater than 120. These base oils are severely hydrocracked, hydroisomerized, and hydrotreated to crate the best grade of petroleum base oil. These products offer superior stability and molecular uniformity, which makes them ideal for some semi-synthetic lubricants.

Some people consider Group III base oils to be synthetic. The API classifies them as mineral oil since they are derived from crude oil. They do mimic characteristics of synthetic oils including high viscosity indices. A lawsuit between Mobil and Castrol occurred due to Castrol marketing their Syntec lubricant as a synthetic even though it was composed of Group III base oils. In a 1999 ruling, the product was allowed to marketed as a synthetic.

Many people reject the decision and only consider Group IV and Group V base stocks as “synthetic.” Some Group III lubricants outperform Group IV lubricants if they contain excellent anti-wear, anti-oxidant, and other additives. Similar to Group II, Group III base oils have an unofficial Group III+, which consist of Group III oils that have a “Very High Viscosity Index (VHVI).” The VHVI minimum is anywhere between 130-140.

Synthetic Base Oils

Group IV

Group IV base oils are synthetic base oils that composed of polyalphaolefins (PAOs). These products have a viscosity index of 125-200. These base oils are not extracted from crude oil, but made from small uniform molecules. The uniformity and manufacturing of these oils allows for predictable properties that assure performance in tough conditions. These properties include extreme temperature stability, which makes these products ideal for cold and hot weather climates.

Lubricants composed of polyinternalolefins (PIOs) are considered to be in the unofficial Group VI. Similar to PAOs, PIOs use different chemicals in its synthesis process to obtain an even higher viscosity index. Their official API classification would be Group V. Certain food grade lubricants are composed of Group IV PAOs.

Group V

Group V base oils are any base oil that is not classified as a Group I-IV base oil. Common Group V base oils are polyalkylene glycols (PAGs) and various esters. One exception is white oil, which is a very pure lubricant commonly used in cosmetics and food processing. Also used in food grade lubricants, Group V base oils such as PAGs or esters can be used in certain biodegradable base stocks rather than vegetable or seed oils. It is important to note that most PAGs are only compatible with other PAGs.

Key Takeaways

When selecting a lubricant, it is important to understand what base oil is used. Given that the base oil is 80-99% of a lubricant, you should know what base oil you are using. Upgrading the Group III or Group IV could improve performance and reduce consumption. Twin Specialties offers a variety of industrial and specialty lubricants made from a variety of base stocks to meet your operating and budgetary requirements.

Pros & Cons of Biodegradable Lubricants

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In the next installment of our Biodegradable Lubricants series we examine the pros and cons of biodegradable lubricants. How do these lubricants compare to their petroleum-based counterparts? Previously we examined: biodegradability standards, biodegradable base stocks and biodegradable lubricant products. However, are these products right for you? We will look at some pros and cons to see if biodegradable lubricants are the right choice for you.

Pros of Biodegradable Lubricants

  • Excellent lubricity; superior to that of mineral oil
  • Higher viscosity index than mineral and synthetic oils
  • Higher flash point than mineral and synthetic oils
  • Less toxic and readily biodegradable
  • Renewable and reduce dependency on imported petroleum
  • New biotechnology has produced genetically-modified seeds designed for use in lubricants
  • Metal-wetting attraction makes them good for keeping dirt and debris off metal surfaces
  • Water-soluble PAGs are ideal for fire-resistant lubricants
  • Ideal for industries and applications where oil comes in contact with the environment
  • No potential for bioaccumulation (build-up in organism fatty tissue)
  • Price premiums are expected to decline with further market development

Cons of Biodegradable Lubricants

  • Lubricity so potent, friction modifiers must be added to reduce slippage in certain applications
  • Insufficient oxidative stability; oil must be treated or modified to ensure performance (which increase costs)
  • Small amounts of water can cause serious foaming and degradation
  • Cannot withstand high reservoir temperatures (usually greater than 80 C)
  • Vegetable base stocks must be hydrogenated to combat low oxidative stability
  • Low pour point; can be improved by winterization
  • Synthetic esters can be used for cold-temperature environments, but reduce bio-based properties
  • Synthetic oils are limited to which additives they can use due to biodegradability standards
  • PAGs can emulsify water, which can cause foaming, sludge, and corrosion
  • High price premiums for synthetic-based products

Conclusion

Biodegradable lubricants have significant potential to perform better than mineral oils. Developments in biotechnology could allow for specially formulated base oils that will address the current short comings of vegetable oils. As demand increases, price premiums will decrease and the we will become less dependent on petroleum. Synthetic oils already provide superior performance, albeit at a higher cost. Environmental concerns will drive these developments and shift the lubricant market towards biodegradable and environmentally accepted lubricants. To learn more, check out this EPA report on Environmentally Accepted Lubricants (EALs).

Twin Specialties Offers Biodegradable Lubricants

No matter your application or environmental requirements, Twin Specialties can meet your manufacturing, marine, or agricultural needs. We offer a variety of lubricants including: Shell Naturelle, Castrol Performance Bio, and various Food Grade lubricants. Contact Twin Specialties for a quote.

What are Biodegradable Lubricants?

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As the world’s petroleum reserves are extracted, scarcity increases, thus driving oil and lubricant prices higher. This economic burden will force end-users and manufacturers to develop alternatives that are cost effective, readily available, and sustainable. The answer to these concerns are biodegradable lubricants.

Biodegradable Lubricants Defined

Biodegradable lubricants have the ability to degrade naturally by the actions of biological organisms. Petroleum is naturally occurring and is considered inherently biodegradable. However, that does not mean they can be marketed, sold, and treated as biodegradable. When we refer to biodegradable lubricants, we are discussing lubricants that are readily biodegradable.

Determining Biodegradability

Biodegradable lubricants must meet the ISO 9439 or OECD 301B standards. These standards state that a lubricant that has degraded by more than 60% within 28 days is readily biodegradable. The tests involve treating a lubricant sample with microorganisms in the presence of oxygen and measuring the CO2 produced by the microorganisms. As mentioned before, petroleum-based lubricants are inherently biodegradable, but not readily biodegradable because they fail to meet these standards. Petroleum-based lubricants naturally degrade at a rate of 15-35% in 28 days, falling short of the required 60%.

Additionally, the lubricant must be of “low toxicity.” There are a variety of tests used to determine toxicity. These tests involve fish, daphnia, and other organisms. In their pure form, mineral oil and vegetable oil show little toxicity, but lubricants are not just pure oil. As additives are incorporated into formulations, the toxicity increases. Additives are added to make up for any performance shortcomings of biodegradable base stocks.

Types of Biodegradable Base Stocks

Most biodegradable lubricants use vegetable oil, synthetic esters, polyalkylene glycols (PAGs), or a combination of these as base stocks. Vegetable oils have been used for years when petroleum was in short supply. They were popular during World War I and World War II due to oil rationing and came back in popularity during oil embargo in the 1970s. Vegetable oils declined in popularity due to the availability of low-cost oil after Desert Storm. Their popularity is beginning to rise as more manufacturers and end-users are faced with climate change and sustainability concerns. Some common vegetable oils used are soybean oil, cottonseed oil, olive oil, sunflower oil, and canola oil. To improve performance, farmers are beginning to grow genetically modified crops that are designed and engineered for use in lubricants.

Synthetic base stocks, such as esters and PAGs, are also used to boost performance when vegetable oils cannot get the job done. PAGs are effective, however they have a few issues that should be considered. PAGs are incompatible with other oils and can cause problems if inadvertently mixed with non-PAG oils. PAGs can also react poorly with seals and paints. This is why synthetic esters are preferred for biodegradable lubricants. Synthetic esters are typically added to vegetable-oil based lubricants to improve low temperature properties. These serve better than light mineral oils as synthetic esters are less toxic and more biodegradable.

Biodegradable Lubricant Products

Many applications and machines now can be lubricated with biodegradable lubricants and meet all performance requirements. Products that can be composed of soybean oils include:

  • Food grade hydraulic fluids and greases
  • Automotive, railroad, and machine greases
  • Tractor transmission and industrial hydraulic fluids
  • Chainsaw bar oils
  • Gear lubricants
  • Compressor oils
  • Transmission and transformer line cooling fluids

Many more products are in development and could become viable in lubricant markets soon. These include:

  • Two-cycle engine oils
  • Metalworking fluids
  • Specialty lubricants

With more resources and demand for biodegradable lubricants, engineers and manufacturers can research and develop more products that perform more applications, perform better than mineral oils, and remain price competitive.

Biodegradable lubricants are highly popular in applications and industries where environmental and safety concerns are high. Marine and agricultural industries need these lubricants as contamination could have devastating effects. According to Total Lubricants, a single liter of oil can pollute as much as 1,000,000 liters of water. In those applications, biodegradable lubricants are essential. Some government regulations ensure that these industries use biodegradable lubricants that do not harm consumers and operators in the event of leakage.

Twin Specialties Offers Biodegradable Lubricants

No matter your application or environmental requirements, Twin Specialties can meet your manufacturing, marine, or agricultural needs. We offer a variety of lubricants including: Shell Naturelle, Castrol Performance Bio, and various Food Grade lubricants. Contact Twin Specialties for a quote.

What are Aerospace Lubricants?

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On May 30, 2020, NASA and SpaceX partnered to send American astronauts from US soil to the International Space Station for the first time since 2011. As a new era spaceflight begins, government entities like NASA and private enterprises like SpaceX will work to innovate their rockets and push boundaries for human space flight. Lubricant manufacturers are tasked with the same challenges to create lubricants that will aid in the journey to reach our ambitious goals.

What are Aerospace Lubricants?

Lubricants in used in aerospace applications such as, space travel, commercial airlines, and defense, are like other lubricants, but face more stringent performance demands. In order to be classified as an aerospace lubricant, products must pass tests that are created by the Department of Defense (DoD) known as “MILSPECS.” To ensure safety and performance for aerospace applications, the MILSPECS create standardization to meet DoD objectives. These MILSPECS test different performance factors such as: corrosion protection, shear stability, compatibility, and water sensitivity.

What Differentiates Aerospace Lubricants?

In addition to meeting various MILSPECS, aerospace lubricants are engineered specifically for aircraft engines and fuel systems. The key difference between aerospace lubricants and non-aerospace lubricants is weight. In space operations, weight is crucial because more fuel is needed, which can become costly. It could also put a strain on how many other supplies could be included in the launch. As the safety of astronauts and functionality of equipment is vital, these lubricants cannot fail.

In space applications, lubricants face the most demanding tests. With temperatures in space at near Absolute-Zero and reentry temperatures reaching 5000 F, lubricants must perform in a wider-range of temperatures than their Earth-bound equivalents. Additionally, lubricants must be able to operate in a vacuum environment. This is on top of all of the crucial navigational and life-supporting machines that make space travel possibly. These machines cannot suffer any breakdowns or down time as they support life and other functions both in space and on Earth. Aerospace lubricants must have a long life to maintain these critical operations.

In defense operations, completing the objective is key and your lubricant must perform to ensure the objective is met. These lubricants have to: withstand extreme-temperature jet engines, cargo aircraft landing gears, precise navigational tools, and other wide-temperature components. By selecting lubricants that meet the right MILSPECS you can ensure proper performance and success in your aerospace operations.

Aerospace Lubricant Manufacturing

Aerospace lubricants in today’s markets can be in the form of liquids or greases. Most use synthetic base oils to achieve desired results and improve efficiency. Most of these lubricants are made of perfluoropolyether (PFPEs) or Multiply Alkylated Cyclopentane (MACs). Several large manufacturers produce these products that meet various MILSPECS. Twin Specialties has access to a wide variety aerospace and MILSPEC lubricants from Shell and Castrol. Contact us to learn more about our catalog.