Category: Biodegradable Lubricants

Pros & Cons of Biodegradable Lubricants

Posted on by Twin Specialties in Biodegradable Lubricants, Blog Tagged , , , , , ,

In the next installment of our Biodegradable Lubricants series we examine the pros and cons of biodegradable lubricants. How do these lubricants compare to their petroleum-based counterparts? Previously we examined: biodegradability standards, biodegradable base stocks and biodegradable lubricant products. However, are these products right for you? We will look at some pros and cons to see if biodegradable lubricants are the right choice for you.

Pros of Biodegradable Lubricants

  • Excellent lubricity; superior to that of mineral oil
  • Higher viscosity index than mineral and synthetic oils
  • Higher flash point than mineral and synthetic oils
  • Less toxic and readily biodegradable
  • Renewable and reduce dependency on imported petroleum
  • New biotechnology has produced genetically-modified seeds designed for use in lubricants
  • Metal-wetting attraction makes them good for keeping dirt and debris off metal surfaces
  • Water-soluble PAGs are ideal for fire-resistant lubricants
  • Ideal for industries and applications where oil comes in contact with the environment
  • No potential for bioaccumulation (build-up in organism fatty tissue)
  • Price premiums are expected to decline with further market development

Cons of Biodegradable Lubricants

  • Lubricity so potent, friction modifiers must be added to reduce slippage in certain applications
  • Insufficient oxidative stability; oil must be treated or modified to ensure performance (which increase costs)
  • Small amounts of water can cause serious foaming and degradation
  • Cannot withstand high reservoir temperatures (usually greater than 80 C)
  • Vegetable base stocks must be hydrogenated to combat low oxidative stability
  • Low pour point; can be improved by winterization
  • Synthetic esters can be used for cold-temperature environments, but reduce bio-based properties
  • Synthetic oils are limited to which additives they can use due to biodegradability standards
  • PAGs can emulsify water, which can cause foaming, sludge, and corrosion
  • High price premiums for synthetic-based products

Conclusion

Biodegradable lubricants have significant potential to perform better than mineral oils. Developments in biotechnology could allow for specially formulated base oils that will address the current short comings of vegetable oils. As demand increases, price premiums will decrease and the we will become less dependent on petroleum. Synthetic oils already provide superior performance, albeit at a higher cost. Environmental concerns will drive these developments and shift the lubricant market towards biodegradable and environmentally accepted lubricants. To learn more, check out this EPA report on Environmentally Accepted Lubricants (EALs).

Twin Specialties Offers Biodegradable Lubricants

No matter your application or environmental requirements, Twin Specialties can meet your manufacturing, marine, or agricultural needs. We offer a variety of lubricants including: Shell Naturelle, Castrol Performance Bio, and various Food Grade lubricants. Contact Twin Specialties for a quote.

What are Biodegradable Lubricants?

Posted on by Twin Specialties in Biodegradable Lubricants, Blog Tagged , , , , , , , , , , ,

As the world’s petroleum reserves are extracted, scarcity increases, thus driving oil and lubricant prices higher. This economic burden will force end-users and manufacturers to develop alternatives that are cost effective, readily available, and sustainable. The answer to these concerns are biodegradable lubricants.

Biodegradable Lubricants Defined

Biodegradable lubricants have the ability to degrade naturally by the actions of biological organisms. Petroleum is naturally occurring and is considered inherently biodegradable. However, that does not mean they can be marketed, sold, and treated as biodegradable. When we refer to biodegradable lubricants, we are discussing lubricants that are readily biodegradable.

Determining Biodegradability

Biodegradable lubricants must meet the ISO 9439 or OECD 301B standards. These standards state that a lubricant that has degraded by more than 60% within 28 days is readily biodegradable. The tests involve treating a lubricant sample with microorganisms in the presence of oxygen and measuring the CO2 produced by the microorganisms. As mentioned before, petroleum-based lubricants are inherently biodegradable, but not readily biodegradable because they fail to meet these standards. Petroleum-based lubricants naturally degrade at a rate of 15-35% in 28 days, falling short of the required 60%.

Additionally, the lubricant must be of “low toxicity.” There are a variety of tests used to determine toxicity. These tests involve fish, daphnia, and other organisms. In their pure form, mineral oil and vegetable oil show little toxicity, but lubricants are not just pure oil. As additives are incorporated into formulations, the toxicity increases. Additives are added to make up for any performance shortcomings of biodegradable base stocks.

Types of Biodegradable Base Stocks

Most biodegradable lubricants use vegetable oil, synthetic esters, polyalkylene glycols (PAGs), or a combination of these as base stocks. Vegetable oils have been used for years when petroleum was in short supply. They were popular during World War I and World War II due to oil rationing and came back in popularity during oil embargo in the 1970s. Vegetable oils declined in popularity due to the availability of low-cost oil after Desert Storm. Their popularity is beginning to rise as more manufacturers and end-users are faced with climate change and sustainability concerns. Some common vegetable oils used are soybean oil, cottonseed oil, olive oil, sunflower oil, and canola oil. To improve performance, farmers are beginning to grow genetically modified crops that are designed and engineered for use in lubricants.

Synthetic base stocks, such as esters and PAGs, are also used to boost performance when vegetable oils cannot get the job done. PAGs are effective, however they have a few issues that should be considered. PAGs are incompatible with other oils and can cause problems if inadvertently mixed with non-PAG oils. PAGs can also react poorly with seals and paints. This is why synthetic esters are preferred for biodegradable lubricants. Synthetic esters are typically added to vegetable-oil based lubricants to improve low temperature properties. These serve better than light mineral oils as synthetic esters are less toxic and more biodegradable.

Biodegradable Lubricant Products

Many applications and machines now can be lubricated with biodegradable lubricants and meet all performance requirements. Products that can be composed of soybean oils include:

  • Food grade hydraulic fluids and greases
  • Automotive, railroad, and machine greases
  • Tractor transmission and industrial hydraulic fluids
  • Chainsaw bar oils
  • Gear lubricants
  • Compressor oils
  • Transmission and transformer line cooling fluids

Many more products are in development and could become viable in lubricant markets soon. These include:

  • Two-cycle engine oils
  • Metalworking fluids
  • Specialty lubricants

With more resources and demand for biodegradable lubricants, engineers and manufacturers can research and develop more products that perform more applications, perform better than mineral oils, and remain price competitive.

Biodegradable lubricants are highly popular in applications and industries where environmental and safety concerns are high. Marine and agricultural industries need these lubricants as contamination could have devastating effects. According to Total Lubricants, a single liter of oil can pollute as much as 1,000,000 liters of water. In those applications, biodegradable lubricants are essential. Some government regulations ensure that these industries use biodegradable lubricants that do not harm consumers and operators in the event of leakage.

Twin Specialties Offers Biodegradable Lubricants

No matter your application or environmental requirements, Twin Specialties can meet your manufacturing, marine, or agricultural needs. We offer a variety of lubricants including: Shell Naturelle, Castrol Performance Bio, and various Food Grade lubricants. Contact Twin Specialties for a quote.