3 Factors for Perfecting Aqueous Cleaning

When cleaning finished machine parts, manufacturers have to meet the increasingly stringent cleanliness tolerances, while also operating a cost-effective cleaning process. Old standards no longer apply and manufacturers have to evaluate their operations to select the best cleaning process. Just utilizing best practices and monitoring your tank is not enough.

The first thing that should be assessed is the contamination generated in all stages of the manufacturing process. Engineers should have data on all processes and substances that parts have been exposed to. Cleaner and equipment suppliers should have reliable lab work to help understand the process and contaminants. Equipment and cleaner manufacturers should provide transparent testing and results to demonstrate the value and effectiveness of their solution.

The 3 Cleaning Energies

Every cleaning process will depend on a balance of 3 energies: chemical, thermal, and mechanical. If one form of energy is increased, the other two forms of energy can typically be reduced. The key to perfecting your aqueous cleaning process will be balancing the 3 energies.

Chemical Energy

Chemistry should be the first consideration in developing a cleaning process. The part material and contamination will determine the appropriate pH range of your aqueous cleaner. The goal is to minimize chemistry at the lowest temperatures and least costly form of mechanical energy to achieve cleanliness standards in the required time cycle.

Alkaline cleaners (pH 9-14) are ideal for removing organic contaminants such as oils, greases, coolants, etc. Acidic cleaners (pH 1-6) are ideal for removing inorganic contaminants such as oxides and rust. Neutral cleaners are excellent for use in systems that use more mechanical energy such as ultrasonic cleaning.

Depending on the part material, less or more aggressive cleaners will be appropriate. More neutral chemistries should be considered for softer and more reactive metals, such as aluminum, copper, or brass. A more aggressive chemistry could start attacking/reacting with the part itself. Less reactive metals can withstand stronger chemistries, higher temperatures, and more mechanical energy. Inert chemistries will require more mechanical energy to drive reactions and break down contaminants.

Thermal Energy

Heat is controlled in a cleaning system by different heating elements. What elements and how they are programmed are dependent on your goals and system. It is important to carefully monitor temperatures to prevent reduced heat element life and temperature capacity. Sensors and controllers are recommended to monitor cleaning systems and can help prolong service life and improve performance.

Heat increases the speed of molecules and faster molecules are better at breaking down bonds of contaminants. For every 17 F increase in temperature, reaction rates can double. This can accelerate the cleaning process. The optimal temperature in most systems is 120 F to 160 F. Too low of temperatures can lead to foaming and less effective cleaning.

Increased heat can reduce drying times and accelerate the cleaning process. It is important to remove pools of water using gravity or airflow. However, too hot of temperatures could create “flash rusting,” which can lead to parts being deemed off-spec or require additional cleaning or work.

Mechanical Energy

The final piece of the puzzle is mechanical energy. This is determined by the equipment and process that is used. Vertical agitators are popular because of their forgiveness and ability to avoid oil loading. The main way to generate mechanical energy is creating agitation.

In immersion cleaning systems, agitation is created by moving the parts in and out or within a tank of cleaner. Spray washers introduce agitation by introducing energy into the cleaner by spraying it at high speeds onto parts. Spray washers can be used in conveyer systems that have multiple stages, such as washing, rinsing, and rust inhibiting.

Ultrasonic cleaning introduce the most mechanical energy and are ideal for cleaning processes with limited heat and less aggressive chemistry. Ultrasonic cleaning should be considered when conventional methods fail to meet cleanliness tolerances.

Conclusion

Balancing the three energies is key to perfecting a cleaning process. When selecting an aqueous cleaner, consider your equipment, process, contaminants, and part material. Twin Specialties offers a full-line of aqueous cleaners that can fit any cleaning process. Many cleaners are specifically designed for ultrasonic, spray, and/or immersion cleaning process. Contact Twin Specialties to learn more about our aqueous cleaners and see what product is right for you.

How to Monitor Alkaline Cleaning Tanks

After machining parts, manufacturers have to clean them. Once clean, the parts may be painted, assembled, or stored with a rust inhibitor coating. That makes cleaning crucial. Poor cleaning could lead to rust, uneven painting or failure in assembly. Many manufacturers do not have the time or budget to rapidly change out (1-day to 1-week intervals) cleaning tanks; if you are fortunate to have short intervals, little maintenance is required as there is limited time for problems to arise. However, you should still perform basic tests to ensure your cleaner is working properly.

For manufacturers with longer tank life, there are 2 main properties to monitor to ensure the performance of your alkaline cleaner: pH and concentration. When the pH and concentration change, the efficacy of the cleaners can decline and lead to more frequent change-outs and greater cleaner consumption. Basic monitoring can prove to be highly cost effective and extend tank life. 

pH Testing

The ability to remove soils declines as the cleaner’s pH drops. The recommended pH for cleaning non-aluminum parts is > 9.0 and > 9.5 for aluminum parts. Additionally, many corrosion inhibitors have a pH-dependent solubility curve. As the pH drops, less inhibitor is incorporated into the solution and the more likely corrosion on cleaned parts can occur. These inhibitors start to drop around 10.2 pH, but do not cause significant issues until the pH drops below 9.5.

Maintenance programs typically attempt to adjust the pH back into range after falling out rather than monitoring the pH for remaining in range. We recommend the latter method as this ensures the pH does not drop dangerously low and potentially renders the solution unusable. Trying to keep the pH between 9.5 (or higher) and 10.5 is ideal. Adding a caustic to boost pH could cause problems as you will get a false concentration reading. If you plan to adjust the pH, have a qualified on-site analytical chemist perform the adjustments.

To measure the pH, pull a sample of agitated solution and wait for it to cool to room temperature. Once cooled, use a narrow range pH strip to test the pH. Higher temperatures can render pH tests unreliable and measuring in the tank could capture the pH of contaminants on the strip.

Concentration Testing

The other key test involves testing the concentration using titration. Titration is used to find the tank strength (concentration). Titration involves adding an acidic reagent to a know volume of tank solution until a defined pH is reached. This can be done simply by adding drops of a reagent to the tank solution. This process involves a dye that changes colors at the defined pH endpoint. This is useful for finding the concentration with a +/- 2% tolerance.

This method is rather crude, but can be highly refined by having a trained chemist use lab equipment to run the test. Lab equipment is required for tests that require tighter tolerances than +/- 2%. Look for a constant concentration over time. If the concentration drops, some likely suspects are: cleaner carry-out, leaks, overly aggressive oil skimming, pH degradation by contaminants, and excessive raw material stripping. If the concentration increases, some likely suspects are: excessive add-back of cleaner or the presence of metalworking fluids. Sometimes soil could affect the strength reading and could indicate rising concentration or stable concentration when the strength is actually dropping.

Takeaways

The pH and concentration tests should be conducted each shift in the manner described above. Investing in lab equipment may prove worthwhile if you have stringent tolerances. If the concentration is too low, add some cleaner to put the solution in the proper range. If too high, add water to bring solution within the proper range. pH adjustment is not recommended unless you have a trained chemist on-site. For more information on cleaner management, contact Twin Specialties and ask about our “Coolant Management Guide” that includes tips and information for aqueous cleaners.